Improved measurement of the neutron absorption cross section for very low velocities

The absorption cross section of natural Gd and isotopic enriched 157Gd for ultra-cold neutrons (UCN) as a function of the velocity has been measured within a time-of-flight-experiment. Particular attention is paid to small velocities in the region of a few m/s. This is intended to determine the validity of the 1/v-law governing absorption cross sections in this region and the resulting divergence at v=0. The experiment does not show any significant violation of 1/v for v>3 m/s

Bonding and Catalytic Application of Ruthenium N-Heterocyclic Carbene Complexes Featuring Triazole, Triazolylidene, and Imidazolylidene Ligands

The first mixed normal/abnormal NHC ruthenium(II) complexes bearing triazole/imidazole-based ligands are presented. The ruthenium complexes show differing coordination geometries depending on the ligand sphere and the coordination of the triazole. Two Ru(II) monocarbene complexes have been obtained, with a 2-imidazolylidene carbene and the 1,2,3-triazoles acting as neutral nitrogen donors. In addition, a tridentate Ru(II) complex featuring a normal 2-imidazolylidene as well as two abnormal 1,2,3-triazolylidene carbene moieties is described. Both structural motifs are evaluated in transfer hydrogenation of acetophenone, with the electron-rich Ru(II) tri-NHC exhibiting the highest conversion